Mecanismos Animados

Capítulo 03
Chlorination of Methane
Capítulo 04
Cyclohexane Ring Flip Cyclohexane Potential Energy Diagram Chlorination of Methane Cis-Dimethylcyclohexane Trans-dimethylcyclohexane
Capítulo 06
Does concerted attack occur from the front? Concerted attack on a chiral R reactant from the front gives an R product Concerted attack on a chiral R reactant from the back gives an S product Reaction mechanism shown in symbolic detail Change in potential energy during reaction mechanism Ball & stick and space-filling representations of reaction mechanism Role of methanol solvent in reducing nucleophilicity Role of DMF solvent in increasing nucleophilicity
Capítulo 07
Reaction mechanisms shown in symbolic detail Change in potential energy during reaction mechanism Ball & stick representation of back- and frontside nucleophilic attack Reaction mechanism shows why a chiral reactant leads to a racemic product Reaction mechanism shown in symbolic detail Ball & stick and space-filling representations of reaction mechanism
Capítulo 08
Reduction of cyclobutanone with lithium aluminum hydride Formation of Grignard reagent from 1-bromobutane and reaction with acetaldehyde to give 2-hexanol Reduction of pentanal with sodium borohydride
Capítulo 09
Mechanism of alcohol dehydration Mechanism of carbocation rearrangement
Capítulo 12
Reaction mechanism shown in symbolic detail Ball & stick and space-filling representations of reaction mechanism Mechanism of hydroboration-odation Oacyclopropanation Mechanism of ozonolysis Radical hydrobromination of propene Brominationofcis-2-butene Brominationoftrans-2-butene Cyclobutene Stereospecific bromination of 2-butenes
Capítulo 14
Addition of HBr to 1,3-butadiene Cis-dimethylcyclobutene Trans,cis,trans-2,4,6-Octatriene Mechanism of the Diels-Alder cycloaddition (endo rule) Radical allylic halogenation Diels-Aldercis,cis-hexadieneexoendo Diels-Aldercis,trans-hexadieneexoendo Diels-Aldertrans,trans-hexadieneexoendo Diels-AldercyclopentadieneDMAD Diels-AlderCyclpentadieneMAeoendo Heatrieneclosure
Capítulo 15
Electrophilic aromatic sulfonation of benzene 1 Electrophilic aromatic sulfonation of benzene 2
Capítulo 16
Electrophilic aromatic substitution of benzenamine (ortho vs meta vs para) Electrophilic aromatic substitution of benzoic acid (ortho vs meta vs para)
Capítulo 17
Mechanism of the Wittig reaction Mechanism of acetal formation
Capítulo 18
Mechanism of the aldol condensation-dehydration Mechanism of Robinson annulation: i.e. Michael addition followed by intramolecular aldol condensation
Capítulo 19
Mechanism of esterification
Capítulo 20
Amide hydrolysis Hofmann rearrangement
Capítulo 21
Mechanism of reductive amination Mechanism of the Mannich reaction
Capítulo 22
Nucleophilic Aromatic Substitution Reaction of Benzylic nucleophilic substitution Nucleophilic Aromatic Substitution via Benzynes Cope Claisen
Capítulo 23
Mechanism of the Claisen condensation
Capítulo 24
Methyl Glycoside Formation Cyclic hemiacetal formation by glucose
Capítulo 26
Chapter 26: Mechanism of the Strecker synthesis